by on December 18, 2024
These outcomes are in line with η5-coordination of the ligand to the metallic centre. Within the case of the substituted cyclopentadienyl ligand, there's considerably larger variation: carbon-carbon bond lengths fluctuate between 1.39 Å and 1.Forty eight Å, the inner bond angles differ between 106° and 111°, and the rhodium-carbon bond lengths differ between 2.14 Å and 2.20 Å. The larger variation in the substituted ligand is attributed to the distortions necessary to relieve the steric strain i...
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